Infographic on the chemistry of onions. As onions are sliced, they release a class of enzymes, allinases, which break down amino acid sulfoxides. A specific compound produced during this process is 1-propenesulfenic acid. 1-propenesulfenic acid is rearranged by another enzyme, called lachrymatory factor synthase, to produce syn-propanethial-S-oxide. Production of this gas peaks 30 seconds after mechanical damage to the onion, and it stimulates sensory neurons in the eye causing a stinging sensation; the eye produces tears to flush it out. Thiosulfinates are the primary flavour and odour producing molecules in an onion. These compounds are not present in intact bulbs, but are formed via enzymatic reaction from sulfur amino acids. Allicin is one of these compounds, which in turn quickly breaks down to form other sulfur-containing compounds.
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The latest in the series of food chemistry graphics looks at the chemistry of onions – specifically, what causes their odour, and why chopping onions will make your eyes water. Interestingly, none of the compounds that cause these effects are present in the intact onion; rather, when the cell walls of the onion are damaged by chopping, an enzyme released produces a range of compounds as a defence mechanism, which act as irritants.

There are a wide range of compounds produced by these reactions, many of which are unstable and only exist fleetingly before breaking down further. If the onion is ingested, these compounds are eventually broken down into allyl methyl sulfide, shown below, which can be removed from the body by exhalation – giving rise to the characteristic ‘onion breath’. Garlic and onion are of course members of the same family (the allium family), so it’s no surprise the same compound is responsible for ‘garlic breath’.

Allyl methyl sulfide
Allyl methyl sulfide

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A modified version of this graphic will appear in ‘The Curious Chemistry of Food & Drink’, available to pre-order now!

References & Further Reading

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